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battery, in electricity and electrochemistry
2023-06-16

battery, in electricity and electrochemistry, any of a class of devices that convert chemical energy directly into electrical energy. Although the term battery, in strict usage, designates an assembly of two or more galvanic cells capable of such energy conversion.

Every battery (or cell) has a cathode, or positive plate, and an anode, or negative plate. These electrodes must be separated by and are often immersed in an electrolyte that permits the passage of ions between the electrodes. The electrode materials and the electrolyte are chosen and arranged so that sufficient electromotive force (measured in volts) and electric current (measured in amperes) can be developed between the terminals of a battery to operate lights, machines, or other devices. Since an electrode contains only a limited number of units of chemical energy convertible to electrical energy, it follows that a battery of a given size has only a certain capacity to operate devices and will eventually become exhausted. The active parts of a battery are usually encased in a box with a cover system (or jacket) that keeps air outside and the electrolyte solvent inside and that provides a structure for the assembly.

Commercially available batteries are designed and built with market factors in mind. The quality of materials and the complexity of electrode and container design are reflected in the market price sought for any specific product. As new materials are discovered or the properties of traditional ones improved, however, the typical performance of even older battery systems sometimes increases by large percentages.

Batteries are divided into two general groups: (1) primary batteries and (2) secondary, or storage, batteries. Primary batteries are designed to be used until the voltage is too low to operate a given device and are then discarded. Secondary batteries have many special design features, as well as particular materials for the electrodes, that permit them to be reconstituted (recharged). After partial or complete discharge, they can be recharged by the application of direct current (DC) voltage. While the original state is usually not restored completely, the loss per recharging cycle in commercial batteries is only a small fraction of 1 percent even under varied conditions.

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